One challenge will be that the front molding will need to be 'deeper' to account for the 10 degree slope to match up properly with the sides.
One of two things will happen on the column, it's a matter of making a decision of what look you are after.
A; the top of the molding profile projection will be narrower than the sides and be difficult to hide on the miter. If a releif cut was made to be perpendicular to the sides, then the typical 45-45 =90 miter would work and the relief cut would hide any discrpency of the miter and molding being shy on the front-top. The molding could be cut, glued, and placed on the column all in one step. This treatment probably wouldn't look noticeable to the viewer since you won't be looking down on it, and you will see the underside more often.
B: If you want to have the same profile projection on the top of the molding aroung the column, the bottom of the molding must be 'made up' to allow for the slope of the column. If you would cut your unaltered moldings at a typical 45 degree miter, then add on a 10 degree backer to the front piece, or put it on the column as a nailer, this should work. This will look 'heavier' from the seated position.
I don't think a compound miter will work in this situation with the applied trim. Crown yes, trim no.