what shape is the finish that's currently on the Windows? Peeling/Alligator paint, or stained on the inside of the window and painted on the outside? Or, decent but faded paint?
As noted, the Rotex mode of the RO 90 would be great for aggresive paint removal if Lead Paint is not an issue.
Neither sander will get into fine detail , which would mean reaching for a small carbide scraper or similar tool.
If the windows are weatheed and need alot of work, I'd reach for the Ro 90 in a heartbeat, esp. if epoxy work like from Abratron is needed. If it's just a case of scuff sanding to prep for painting, and the pad of the DTS 400 fits where you need to go, I'd go with it since it's stable, small, light, and has great dust collection.