www.specialtytools.com will become your friend, especially their "Micron" sandpaper punched with Festool holes. My Corian installer used the 30 Micron paper on the Rotex for most everything. I don't recall seeing any wet sanding.
Rough cut with the saw and always square it up with a router. That's the trick to a perfect seam. Of course, they made it look easy and had the special suction tools, but man, it looked fun, too. Watching them glue a sink to the bottom of the countertop and clamp it through the world's ugliest rough cut hole while the glue setup, then seeing it magically transformed into a perfect surface by a router...it's just cool. I got that same feeling that I used to get when I would put a round edged, fugly set of 12" shaper blades onto the platform of the grinder, flip the switch to hold them in place magnetically, then watch as a perfectly flat, single steel surface emerges.
Once I feel like I've got the "chops" for it, I'm going to fabricate a few smaller countertops for the garage and laundry room out of the Corian leftovers. It does make a different kind of mess, though. Check out the Freeform Furniture episode with the outdoor tables/chairs with solid surface tops and bottoms and glass tile sides.
Look into Samsung Staron, Formica, and WilsonArt's solid surface material, too. I think they're a bit cheaper, but you'd be hard pressed to tell any difference especially for sign work. My main bathroom's countertop is Staron with a vacuum formed Corian basin. I forget what color it was, but they're virtually identical except for the surface finish of the basin.
You can get some good practice pieces at a decent price from eBay. There's always someone on there selling blanks or scraps. Heck, we bought our two bathroom sinks there and got the deal of the century. Two (TPD Brand???), vacuum formed basins for thirty five bucks, shipped. Dealer cost is about $700 each. A big "Thank You" to whomever ordered those and then changed their mind!