I do not own a Kapek and do woodworking as a hobby but I sometimes build furniture including out of maple. I also use oak, cherry, and walnut. Maple and cherry both burn more than softwoods or oak or walnut. I'm not sure why but they do. If my blade is not completely clean, I will get burning. I am normally using a table saw but also use my non-slider 12 inch CMS and RAS for crosscuts. So I think part of the issue may be the wood.
I know it wasn't you but painting maple is a terrible idea. Birch or poplar or softwood are cheaper and take paint at least as well. But you got what you got.
Your saw may be part of the issue or the blade. But I also wonder if part of it is not the paint. I paint softwood moldings before I put them up in the houses I've lived in but I used latex paint. It cuts find and does not gum up my blades. But I wonder if this is not oil based or another type of paint that reacts differently to being cut. It my be gumming the blade really quickly resulting in the burning. Do you know anything about the paint?